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Evolution of a chemical system

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RéférentDidier LUCAS
ECTS2
CM / TD / TP14 / 16 / 8
Typematiere

Viable
Viable100%
Complète71%
Manque pour « complète »
  • Modalités d'évaluation
  • Bibliographie
  • Prérequis
  • Version EN relue

But du cours

Predict the evolution of a chemical system: Is the system at equilibrium? How fast will the system evolve?

Acquis d'apprentissage visés

  • Know how to define state functions H, S, and G
  • Know how to define a reaction quantity
  • Know how to calculate a reaction enthalpy from standard enthalpies of formation
  • Know how to calculate a reaction entropy from standard entropies of pure substances
  • Know how to relate the sign of the reaction enthalpy to the exothermic/endothermic nature
  • Know how to relate the sign of the reaction entropy to the variation in the number of moles of gas
  • Know how to predict the evolution of a system based on the reaction Gibbs free energy
  • Know how to define the terms homogeneous and isothermal
  • Know how to define the rate of appearance of a product/rate of disappearance of a reactant
  • Know how to define the (intensive) reaction rate
  • Know how to present kinetic factors
  • Know how to define a catalyst
  • Know the different types of catalysis
  • Know how to describe the mode of action of a catalyst
  • Know how to describe the selectivity of a catalyst
  • Know that the rate of certain reactions can take a particular form
  • Know how to define the terms partial order and overall order
  • Know how to differentiate overall order and current order
  • Know how to define simple and complex reactions
  • Know that a kinetic study aims to determine the rate constant and the orders
  • Know how to describe the differential method
  • Know how to describe the integral method
  • Know how to apply the integral method to reactions of order 0, 1, and 2
  • Know how to use the half-life to determine a partial order
  • Know how to state Arrhenius' law
  • Know how to use experimental results to determine the activation energy
  • Know how to define the terms endothermic and exothermic

Programme

  1. Elements of thermochemistry
  1. Chemical kinetics (formal kinetics without MR)

Supports

Materials available on the Moodle platform.